(74) Li, Z.-Y.; Hu, L. R.; Liu, Q.-Y.; Ning, C.-G.; Chen, H.*; He, S.-G.*; Yao, J. N. "C−H Bond Activation by Early Transition metal Carbide Cluster Anion MoC₃⁻" Chem. Eur. J. 2015, 21, 17748.

(73) Wang, L.; Hu,L. R.; Zhang, H. Z.; Chen, H.*; Deng, L.* "Three-Coordinate Iron(IV) Bisimido Complexes with Aminocarbene Ligation: Synthesis, Structure and Reactivity" J. Am. Chem. Soc. 2015, 137, 14196.

(72) Liu, Q.-Y.; Hu, L. R.; Chen, H.*; He, S.-G.* "Photoelectron Imaging Spectroscopy of ZrO⁻ Diatomic Anion" Chinese J. Chem. Phys. 2015, 28, 452.

(71) Hu, J. T.; Lan, T. L.; Sun, Y. H.; Chen, H.*; Yao, J. N.; Rao, Y.* "Unactivated C(sp³)-H Hydroxylation through Palladium Catalysis with H₂O as the Oxygen Source" Chem. Commun. 2015, 51, 14929. (RSC Top 25 Most-Downloaded Articles in the online version of Chem. Commun. the third quarter of 2015, Web page accessed on Nov 3^rd 2015, http://blogs.rsc.org/cc/2015/10/29/top-25-chemcomm-articles-july-september-2015/)

(70) Song, C. L.; Sun, Y. H.; Wang, J. W.; Chen, H.*; Yao, J. N.; Tung, C.-H.; Xu, Z. H.* "Successive Cu/Pd Transmetalation Relay Catalysis in Stereoselective Synthesis of Tetraarylethenes" Org. Chem. Front. 2015, 2, 1366.

(69) Hu, L. R.; Chen, H.* "Assessment of DFT Methods for Computing Activation Energies of W/Mo-Mediated Reactions" J. Chem. Theory Comput. 2015, 11, 4601.

(68) Tang, H.; Huang, X.-R.*; Yao, J. N.; Chen, H.* "Understanding the Effects of Bidentate Directing Groups: A Unified Rationale for sp² and sp³ C−H Bond Activations" J. Org. Chem. 2015, 80, 4672.

(67) Liu, Q.-Y.; Hu, L. R.; Li, Z.-Y.; Ning, C.-G.; Ma, J.-B.; Chen, H.*; He, S.-G.* "Photoelectron Imaging Spectroscopy of MoC⁻ and NbN⁻ Diatomic Anions: A Comparative Study" J. Chem. Phys. 2015, 142, 164301.

(66) Sun, Y. Y.; Hu, L. R.; Chen, H.* "Comparative Assessment of DFT Performances in Ru- and Rh-Promoted σ-Bond Activations" J. Chem. Theory Comput. 2015, 11, 1428.

(65) Zhang, J.; Zhao, C. Y.; Liu, H.; Lv, Y. L.; Liu, R. J.; Zhang, S. S.; Chen, H.*; Zhang, G. J.*; Tian, Z. Y.* "Solvatochromic Fluorescence Emission of An Anthranol Derivative without Typical Donor-Acceptor Structure: An Experimental and Theoretical Study" J. Phys. Chem. C 2015, 119, 2761.

(64) Dong, C. H.; Yang, X. Z.*; Yao, J. N.; Chen, H.*"Mechanistic Study and Ligand Design for the Formation of Zinc Formate Complexes from Zinc Hydride Complexes and Carbon Dioxide" Organometallics 2015, 34, 121.

(63) Nie, H.-J.; Yang, W.-W.; Zheng, R.-H.; Shi, Q.; Chen, H.; Yao, J. N.; Zhong, Y.-W.*"Metal Chelation-Assisted Amine-Amine Electronic Coupling through the 4,4'-Positions of 2,2'-Bipyridine" Inorg. Chem. 2015, 54, 1272.

(62) Liu, Y. B.; Hu, L. R.; Chen, H.*; Du, H. F.*"An Alkene-Promoted Borane-Catalyzed Highly Stereoselective Hydrogenation of Alkynes to Give Z- and E-Alkenes" Chem. Eur. J. 2015, 21, 3495.