(87) Wang, C.; Zhao, C. Y.; Hu, L. R.; Chen, H.*"Calculated Mechanism of Cyanobacterial Aldehyde-Deformylating Oxygenase: Asymmetric Aldehyde Activation by a Symmetric Diiron Cofactor" J. Phys. Chem. Lett. 2016, 7, 4427.

(86) Jiang, Q.; Wang, M.; Yang, L.*; Chen, H.*; Mao, L.* "Synergistic Coordination and Hydrogen Bonding Interaction Modulate the Emission of Iridium Complex for Highly Sensitive Glutamine Imaging in Live Cells" Anal. Chem. 2016, 88, 10322.

(85) Li, Y.-K.; Yuan, Z.; Zhao, Y.-X.*; Zhao, C. Y.; Liu, Q.-Y.; Chen, H.*; He, S.-G.* "Thermal Methane Conversion to Syngas Mediated by Rh₁-Doped Aluminum Oxide Cluster Cations RhAl₃O₄⁺" J. Am. Chem. Soc. 2016, 138, 12854.

(84) Zhang, R.; Zhao, C. Y.; Li, X. M.; Zhang, Z. Y.; Ai, X. C.; Chen, H.*; Cao, R.* "A Homoleptic, All-alkynyl-stabilized Highly Luminescent Au₈Ag₈ Cluster with a Single Crystal X-ray Structure" Dalton Trans. 2016, 45, 12772.

(83) Kumar, P.; Lee, Y.-M.; Hu, L. R.; Chen, J. W.; Park, Y. J.; Yao, J. N.; Chen, H.*;Karlin, K. D.*; Nam, W.* "Factors That Control the Reactivity of Cobalt(III)-Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation" J. Am. Chem. Soc.2016, 138, 7753.

(82) Lu, S.-J.; Hu, L. R.; Xu, X.-L.; Xu, H.-G.; Chen, H.; Zheng, W.-J.*"Transition from Exohedral to Endohedral Structures of AuGe_n^- (n = 2-12) Clusters: Photoelectron Spectroscopy and Ab Initio Calculations" Phys. Chem. Chem. Phys. 2016, 18, 20321.

(81) Liu, Q.-Y.; Ma, J.-B.*; Li, Z.-Y.; Zhao, C. Y.; Ning, C.-G.; Chen, H.*; He, S.-G.*"Activation of Methane Promoted by Adsorption of CO on Mo₂C₂⁻ Cluster Anions" Angew. Chem. Int. Ed. 2016, 55, 5760.

(80) Su, X.; Sun Y. H.; Yao, J. N.; Chen, H.*; Chen, C.* "Acid-Promoted Bicyclization of Arylacetylenes to Benzobicyclo[3.2.1] Octanes through Cationic Rearrangements" Chem. Commun. 2016, 52, 4537. 

(79) Sun, Y. H.; Tang, H.; Chen, K. J.; Hu, L. R.; Yao, J. N.; Shaik, S.; Chen, H.* "Two-State Reactivity in Low-Valent Iron-Mediated C-H Activation and the Implications for Other First-Row Transition Metals" J. Am. Chem. Soc. 2016, 138, 3715. (JACS Top 20 Most-Read Articles over the last one month, Web page accessed on April 7^th 2016, http://pubs.acs.org/action/showMostReadArticles?journalCode=jacsat)

(78) Jia, T.; Zhao, C. Y.; He, R.; Chen, H.*; Wang, C.* "Iron-Carbonyl-Catalyzed Redox-Neutral [4+2] Annulation of N−H Imines and Internal Alkynes by C−H Bond Activation" Angew. Chem. Int. Ed. 2016, 55, 5268.

(77) Liu, Z.-X.; Sun, Y. H.; Feng, Y.*; Chen, H.; He, Y.-M.; Fan, Q.-H. "Halogen-Bonding for Visual Chloride Ion Sensing: A Case Study Using Supramolecular Poly(aryl ether) Dendritic Organogel Systems" Chem. Commun.2016, 52, 2269.

(76) Sun, Y. H.; Chen, H.* "DFT Methods to Study the Reaction Mechanism of Iridium-Catalyzed Hydrogenation of Olefins: Which Functional Should be Chosen?" ChemPhysChem 2016, 17, 119.

(75) Wang, H.-X.; Meng, Z.; Xiang, J.-F.; Xia, Y.-X.; Sun, Y. H.; Hu, S.-Z.; Chen, H.*; Yao, J. N.; Chen, C.-F.* "Guest-Dependent Directional Complexation Based on Triptycene Derived Oxacalixarene: Formation of Oriented Rotaxanes" Chem. Sci. 2016, 7, 469.