(61) Xu, S. J.; Chen, K. J.; Chen, H.*; Yao, J. N.; Zhu, X. Z.*"Stereocontrolled Synthesis of Benzo[k]fluoranthenes: An Unexpected Isomerization Mediated by Rhodacyclopentadienes" Chem. Eur. J. 2014, 20, 16442.

(60) Zhou, B. W.; Ma, P. C.; Chen, H.*; Wang, C. Y.* "Amine-Accelerated Manganese-Catalyzed Aromatic C−H Conjugate Addition to α,β-Unsaturated Carbonyls" Chem. Commun. 2014,50, 14558.

(59) Peng, J.; Chen, C.*; Chen, J. J.; Su, X.; Xi, C. J.; Chen, H.*"Cu-catalyzed Arylcarbocyclization of Alkynes with Diaryliodonium Salts through C-C Bond Formation on Inert C_(sp3)-H Bond" Org. Lett. 2014, 16, 3776.

(58) Kang, R. H.; Chen, K. J.; Yao, J. N.*; Shaik, S.; Chen, H.*"Probing Ligand Effects on O-O Bond Formation of Ru-CatalyzedWater Oxidation: A Computational Survey" Inorg. Chem. 2014, 53, 7130.

(57) Ma, B.; Miao, T.; Sun, Y. H.; He, Y.; Liu, J.; Feng, Y.; Chen, H.*; Fan, Q.-H.* "A New Class of Tunable Dendritic Diphosphine Ligands: Synthesis and Applications in the Ru-Catalyzed Asymmetric Hydrogenation of Functionalized Ketones" Chem. Eur. J. 2014, 20, 9969.

(56) Usharani, D.; Lai, W. Z.; Li, C.; Chen, H.; Danovich, D.; Shaik, S.* "A Tutorial for Understanding Chemical Reactivity Through The Valence Bond Approach" Chem. Soc. Rev. 2014, 43, 4968.

(55) He, R.; Jin, X.; Chen, H.*; Huang, Z.-T.; Zheng, Q.-Y.; Wang, C. Y.*; "Mn-Catalyzed Three-Component Reactions of Imines/Nitriles, Grignard Reagents, and Tetrahydrofuran: An Expedient Access to 1,5-Amino/Keto Alcohols" J. Am. Chem. Soc. 2014, 136, 6558.

(54) Tang, H.; Zhou, B. W.; Huang, X.-R.*; Wang, C. Y.*; Yao, J. N.; Chen, H.* "Origins of Selective C(sp2)-H Activation Using Transition Metal Complexes with N,N-Bidentate Directing Groups: A Combined Theoretical-Experimental Study" ACS Catal. 2014, 4, 649.

(53) Sun, Y. H.; Chen, H.* "Performance of Density Functionals for Activation Energies of Re-Catalyzed Organic Reactions" J. Chem. Theory Comput. 2014, 10, 579.